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A highly hydrophilic benzenesulfonic-grafted graphene oxide-based hybrid membrane for ethanol dehydration.

ABSTRACT: A new type of hybrid membrane was prepared by blending sodium alginate (SA) with benzenesulfonic-grafted graphene oxide (BS@GO), which showed higher hydrophilicity and more defects or edges than GO to create channels for the transfer of water molecules. BS@GO was synthesized by reacting aryl diazonium salts with graphene oxide (GO). The BS@GO sheets were aligned parallelly to the membrane surface and affected the interactions between the SA chains. BS@GO could improve the hydrophilicity and pervaporation properties of SA-based hybrid membranes. Also, compared to GO fillers, BS@GO fillers could supply higher water permeance to improve the pervaporation flux and separation factor. For the pervaporation of 90 wt% aqueous ethanol at 343 K, the optimum hybrid membrane with 1.5 wt% BS@GO in the SA matrix showed the maximum permeate flux of 703 ± 89 g m^-2 h^-1 (1.4 times higher than that of an SA membrane), and the highest separation factor was 5480 ± 94 (5.6 times higher than that of the SA membrane). Moreover, the hybrid membrane exhibited good stability and separation ability during long-term testing.

SUBMITTER: Tang L

PROVIDER: S-EPMC9054239 | biostudies-literature | 2020 May

REPOSITORIES: biostudies-literature

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A highly hydrophilic benzenesulfonic-grafted graphene oxide-based hybrid membrane for ethanol dehydration.

Tang Lin L Lu Yingying Y Yao Lulu L Cui Peng P

RSC advances 20200527 34

A new type of hybrid membrane was prepared by blending sodium alginate (SA) with benzenesulfonic-grafted graphene oxide (BS@GO), which showed higher hydrophilicity and more defects or edges than GO to create channels for the transfer of water molecules. BS@GO was synthesized by reacting aryl diazonium salts with graphene oxide (GO). The BS@GO sheets were aligned parallelly to the membrane surface and affected the interactions between the SA chains. BS@GO could improve the hydrophilicity and perv ...[more]

PMID: 35520457

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Project description:Wound dressings composed of natural polymers, such as type I collagen, possess good biocompatibility, water holding capacity, air permeability, and degradability, and can be used in wound repair. However, due to the persistent oxidative stress in the wound area, the migration and proliferation of fibroblasts might be suppressed, leading to poor healing. Thus, collagen-containing scaffolds are not suitable for accelerated wound healing. Antioxidant N-acetyl cysteine (NAC) is known to reduce the reactive oxygen species (ROS) and has been widely used in the clinic. Theoretically, the carboxyl group of NAC allows loading of graphene oxide (GO) for sustained release and may also enhance the mechanical properties of the collagen scaffold, making it a better wound-dressing material. Herein, we demonstrated an innovative approach for a potential skin-regenerating hybrid membrane using GO incorporated with collagen I and NAC (N-Col-GO) capable of continuously releasing antioxidant NAC. Methods: The mechanical stability, water holding capacity, and biocompatibility of the N-Col-GO hybrid membrane were measured in vitro. A 20 mm rat full-skin defect model was created to evaluate the repair efficiency of the N-Col-GO hybrid membrane. The vascularization and scar-related genes in the wound area were also examined. Results: Compared to the Col only scaffold, N-Col-GO hybrid membrane exhibited a better mechanical property, stronger water retention capacity, and slower NAC release ability, which likely promote fibroblast migration and proliferation. Treatment with the N-Col-GO hybrid membrane in the rat wound model showed complete healing 14 days after application which was 22% faster than the control group. HE and Masson staining confirmed faster collagen deposition and better epithelization, while CD31 staining revealed a noticeable increase of vascularization. Furthermore, Rt-PCR demonstrated decreased mRNA expression of profibrotic and overexpression of anti-fibrotic factors indicative of the anti-scar effect. Conclusion: These findings suggest that N-Col-GO drug release hybrid membrane serves as a better platform for scarless skin regeneration.

Dataset Information

A highly hydrophilic benzenesulfonic-grafted graphene oxide-based hybrid membrane for ethanol dehydration.

Publications

A highly hydrophilic benzenesulfonic-grafted graphene oxide-based hybrid membrane for ethanol dehydration.

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