Hierarchical Co(OH)₂@NiMoS₄ nanocomposite on carbon cloth as electrode for high-performance asymmetric supercapacitors.

ABSTRACT: Hierarchical Co(OH)₂@NiMoS₄ nanocomposites were successfully prepared on a carbon cloth by using a simple two-step hydrothermal method coupled with a room-temperature vulcanization method. The resulting nanocomposites were composed of large-scale uniform Co(OH)₂ nanowires fully covered with ultrathin vertical NiMoS₄ nanoflakes. Because of the synergetic effect between Co(OH)₂ and NiMoS₄, the nanocomposites exhibited good electrochemical performance as a supercapacitor electrode. In particular, a specific capacity of 2229 F g^-1 was achieved at a current density of 1 A g^-1. In addition, an asymmetrical supercapacitor fabricated using activated carbon as the negative electrode and the as-synthesised nanocomposite as the positive electrode exhibited a maximum energy density of 59.5 W h kg^-1 at a power density of 1 kW h kg^-1 and excellent cycling stability (100% capacitance retention after 5000 cycles). These results indicate that the hierarchical Co(OH)₂@NiMoS₄ nanocomposite has great potential for practical application in high-performance energy storage devices.

SUBMITTER: Li J 

PROVIDER: S-EPMC9054593 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature