Efficient Ce-Co composite oxide decorated Au nanoparticles for catalytic oxidation of CO in the simulated atmosphere of a CO₂ laser.

ABSTRACT: Gold nanoparticles have a high activity for CO oxidation, making them suitable to be used in a CO₂ laser which maintains its efficiency and stability via the recombination of CO and O₂ produced by the CO₂ decomposition. However, the high concentration of CO₂ in the working environment greatly reduces the activity of the catalyst and makes the already unstable gold nanoparticles even more so. A novel Au/Ce-Co-O _x /Al₂O₃ gold catalyst, prepared by a deposition precipitation method in this study, displays high activity and good stability for CO oxidation in a simulated atmosphere of a CO₂ laser with the feed gases containing a high concentration of CO₂ up to 60 vol% but a low concentration of O₂ for the stoichiometric reaction with CO. An excellent performance for CO oxidation under CO₂-rich conditions could be achieved by decorating the surface of the Al₂O₃ support with Ce-Co composite oxides. The strong interaction between gold and the composite support, accompanied by the increase of labile lattice oxygen species and the decrease of surface basicity, led to a high CO oxidation rate and resistance towards CO₂ poisoning.

SUBMITTER: Fang Q 

PROVIDER: S-EPMC9054625 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature