Type II porous ionic liquid based on metal-organic cages that enables L-tryptophan identification.

ABSTRACT: Porous liquids with chemical separation properties are quite well-studied in general, but there is only a handful of reports in the context of identification and separation of non-gaseous molecules. Herein, we report a Type II porous ionic liquid composed of coordination cages that exhibits exceptional selectivity towards L-tryptophan (L-Trp) over other aromatic amino acids. A previously known class of anionic organic-inorganic hybrid doughnut-like cage (HD) is dissolved in trihexyltetradecylphosphonium chloride (THTP_Cl). The resulting liquid, HD/THTP_Cl, is thereby composed of common components, facile to prepare, and exhibit room temperature fluidity. The permanent porosity is manifested by the high-pressure isotherm for CH₄ and modeling studies. With evidence from time-depen

SUBMITTER: Zhang Z 

PROVIDER: S-EPMC9054828 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature