A dual emission metal-organic framework for rapid ratiometric fluorescence detection of CO₃ ^2- in seawater.

ABSTRACT: A dual emission metal-organic framework (IRMOF-10-Eu) was prepared and used as a ratiometric fluorescent sensor for CO₃ ^2- detection. IRMOF-10-Eu had good stability and excellent luminescence in aqueous solution. IRMOF-10-Eu showed dual fluorescence emission from the ligand and Eu³⁺ with single excitation. Upon treatment with CO₃ ^2-, the fluorescence ratio (I ₆₂₄/I ₃₅₈) of the probe displayed significant change. The relative fluorescence intensity ratio (I ₆₂₄/I ₃₅₈) and CO₃ ^2- concentration had a linear relationship in 50-300 μM range with a low detection limit of 9.58 μM. And the luminescence probe of CO₃ ^2- showed a fast detection time. The possible mechanism was investigated. CO₃ ^2- changed the structure of IRMOF-10-Eu and interrupted the energy transfer process. Thus, the fluorescence emission intensity of the ligand was increased and Eu³⁺ was decreased with the addition of CO₃ ^2-. IRMOF-10-Eu was used to detect CO₃ ^2- in seawater, which showed good prospect in practical application. Subsequently, a highly selective and sensitive probe, IRMOF-10-Eu, may pave an efficient way for CO₃ ^2- detection in seawater.

SUBMITTER: Wei Y 

PROVIDER: S-EPMC9055149 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature