Globally stabilized bent carbon-carbon triple bond by hydrogen-free inorganic-metallic scaffolding Al₄F₆.

ABSTRACT: For over 100 years, known bent C[triple bond, length as m-dash]C compounds have been limited to those with organic (I) and all-carbon (II) scaffoldings. Here, we computationally report a novel type (III) of bent C[triple bond, length as m-dash]C compound, i.e., C₂Al₄F₆-01, which is the energetically global minimum isomer and bears an inorganic-metallic scaffolding and unexpected click reactivity.

SUBMITTER: Xue YY 

PROVIDER: S-EPMC9055247 | biostudies-literature | 2020 Jun

REPOSITORIES: biostudies-literature