Optical properties of 3-substituted indoles.

ABSTRACT: The optical properties of various donor or acceptor p-phenyl substituted ethenyl indoles were studied in solvents of varying polarity using absorption, fluorescence and TDDFT methods. Ethenyl indole exhibits non-linear optical properties (NLO) in a substituent dependent manner. Compound with a strong electron-attracting substituent, shows large NLO properties with charge transfer behavior, whereas ethenyls with moderate electron withdrawing or electron donating substituent exhibit lower NLO properties with non polar excited state. A highly dipolar excited state for p-nitro phenyl substituted ethenyl indoles (μ _e: 18.2-27.1 debye; Δμ: 9.4-17.8 debye) is observed as compared to other ethenyls (μ _e: 6.6-9.5 debye; Δμ: 4.2-6.2 deb

SUBMITTER: Kumar J 

PROVIDER: S-EPMC9055839 | biostudies-literature | 2020 Jul

REPOSITORIES: biostudies-literature