Enhanced charge storage properties of ultrananocrystalline diamond films by contact electrification-induced hydrogenation.

ABSTRACT: We report the enhanced charge storage characteristics of ultrananocrystalline diamond (UNCD) by contact electrification-induced hydrogenation. The non-catalytic hydrogenation of UNCD films was achieved by using platinum as an electron donor and sulfuric acid as a hydrogen proton donor, confirmed by Raman spectroscopy and time-of-flight secondary ion mass spectroscopy (TOF-SIMS). Chemical treatment with only a H₂SO₄ solution is responsible for the surface oxidation. The oxidation of UNCD resulted in an increase in the quantity and duration of the tribocharges. After non-catalytic hydrogenation, the generation of friction-induced tribocharges was enhanced and remained for three hours and more. We show that the hydrogen incorporation on grain boundaries is responsible fo

SUBMITTER: Kim JE 

PROVIDER: S-EPMC9056710 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature