Research on the mechanism and reaction conditions of electrochemical preparation of persulfate in a split-cell reactor using BDD anode.

ABSTRACT: Through a cyclic voltammetry (CV) curve, electron spin resonance spectroscopy (ESR) characterization and a free radical competitive trapping experiment, an analysis was performed on the mechanism of persulfate (PDS) electro-synthesis by sulfate at a boron-doped diamond (BDD) anode. It had been found that there were two pathways of PDS formation. The first was to form PDS through the interaction of sulfate radicals, which were generated from the oxidation reaction mediated by hydroxyl radicals, where the protonized bisulfate ions and sulfuric acid were oxidized by hydroxyl radicals to sulfate radicals. The second was to produce PDS by generating sulfate radicals through the direct loss of electrons from sulfate and bisulfate ions on the electrode surface. In addition, the effects of initial

SUBMITTER: Zhang F 

PROVIDER: S-EPMC9056715 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature