Two 3D Mn-based coordination polymers: synthesis, structure and magnetocaloric effect.

ABSTRACT: Two three-dimensional (3D) coordination polymers, namely Mn^II ₆(CH₃COO)₂(HCOO)₂(IN)₈(C₄H₈O)₂(H₂O) and Mn^III ₆Mn^II ₁₂(μ₃-O)₆(CH₃COO)₁₂(IN)₁₈(H₂O)_7.5 (abbreviated as Mn ^II ₆ and Mn ^II ₁₂ Mn ^III ₆ respectively; HIN = isonicotinic acid), were synthesized by the reaction of Mn(CH₃COO)₂·4H₂O and isonicotinic acid under solvothermal conditions. Magnetic studies revealed that antiferromagnetic interactions may b

SUBMITTER: Li NF 

PROVIDER: S-EPMC9056753 | biostudies-literature | 2020 Sep

REPOSITORIES: biostudies-literature