A pH-stable Ag(i) multifunctional luminescent sensor for the efficient detection of organic solvents, organochlorine pesticides and heavy metal ions.

ABSTRACT: Developing novel luminescent materials for sensitive and rapid detection of heavy metal ions, organic solvents and organochlorine pesticides is vital for environmental monitoring. Herein, a new Ag(i) luminescent coordination polymer [Ag(3-dpyb)(H₃odpa)]·H₂O (LCP 1) (3-dpyb = N,N'-bis(3-pyridinecarboxamide)-1,4-butane, H₄odpa = 4,4'-oxydiphthalic acid) was obtained by a hydrothermal reaction and characterized by single crystal, powder X-ray diffraction, infrared spectroscopy, thermogravimetric analysis and luminescence spectroscopy. LCP 1 is a three-dimensional (3D) supramolecular framework formed from 1D [Ag-3-dpyb-H₃odpa] _n chains and H-bond interactions. The luminescence sensing study of LCP 1 for recognizing organic solvents, organochlorine pesticides and heavy metal ions was performed, which demonstrated it to be a potential luminescent sensor for Hacac, NB, 2,6-DCN, Fe²⁺, Hg²⁺, and Fe³⁺. Fe²⁺, Hg²⁺, and Fe³⁺ in river water were determined using LCP 1 with satisfying recovery.

SUBMITTER: Ma J 

PROVIDER: S-EPMC9058487 | biostudies-literature | 2020 Dec

REPOSITORIES: biostudies-literature