Solid-state AIEnh-circularly polarised luminescence of chiral perylene diimide fluorophores.

ABSTRACT: Solid-state organic fluorescent materials are important for the development of electroluminescent sensing devices. Herein, we report that N,N'-bis((R)-1-phenylethyl)perylene-3,4,9,10-tetracarboxylic diimide [(R,R)-BPP] and its antipode [(S,S)-BPP], which contain extended π-electrons through planar perylenes, emit solid-state aggregation-induced-enhanced (AIEnh) circularly polarised luminescence (CPL) in inorganic (KBr) pellets and organic-polymer-film (PMMA- and myo-IPU-film) states; this CPL is difficult to observe in solution. These chiral perylene fluorophores emit AIEnh-CPL with high dissymmetry factors (g _CPL) (up to 2.4 × 10^-3) and high quantum yields (Φ _F, up to 0.43) in the three

SUBMITTER: Taniguchi A 

PROVIDER: S-EPMC9059715 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature