Influence of the head group on dynamics in surfactant intercalated graphite oxide.

ABSTRACT: The influence of the headgroup on the dynamics of three different alkylammonium cations confined in graphite oxide (GO) was studied by temperature-dependent impedance spectroscopy. X-ray diffraction, X-ray photoelectron spectroscopy, Fourier-transform infrared spectroscopy, thermogravimetry and elemental analysis served to characterize the composites. The alkylammonium cations were connected to the C-O^- group of GO via ionic interactions, and the backbone of the confined molecule was distributed as a flat monolayer with the long axis parallel to the GO layer. Ngai's correlated-state model was used, with asymmetry at low temperature in the loss peaks. The calculated true activation energy of 114 meV ± 6% meV is almost the same as the internal rotation barrier of the alkyl

SUBMITTER: Ai X 

PROVIDER: S-EPMC9059817 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature