Modification of bio-based β-diketone from wheat straw wax: synthesis of polydentate lipophilic super-chelators for enhanced metal recovery.

ABSTRACT: Bio-derived lipophilic polydentate chelators have been synthesized and tested for their chelating ability using a range of metal salts of Cu, Co, Ni, Fe, and Cr. These novel molecules were produced by the Michael addition reaction of 14,16-hentriacontanedione, isolated from wheat straw wax, with methyl acrylate or bio-derived dimethyl itaconate via microwave heating. The Michael adducts could either be used directly as esters or be hydrolysed to their acid form. Critically, the creation of additional binding sites via the carboxylate moieties leads to an enhanced metal uptake over both a non-renewable commercially available lipophilic β-diketone (dibenzoylmethane) and the unmodified hentriacontane-14,16-dione, for the chelation of Fe(iii), Cr(iii) and Ni(ii). The modified β-d

SUBMITTER: Asemave K 

PROVIDER: S-EPMC9060256 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature