Fullerene derivative induced morphology of bulk heterojunction blends: PIPCP:PC₆₁BM.

ABSTRACT: The performance of organic solar cells (OSCs) depends crucially on the morphology in bulk heterojunctions (BHJs), including the degree of crystallinity of the polymer and the amount of each material phase: aggregated donor, aggregated acceptor, and molecular mixed donor : acceptor phase. In this paper, we report the BHJ morphology of as-cast blend films incorporating the polymer PIPCP as the donor and [6,6]-phenyl-C₆₁-butyric acid methyl ester (PC₆₁BM) as the acceptor. Tracking the scattering intensity of PC₆₁BM as a function of PC₆₁BM concentration shows that PC₆₁BM aggregates into donor-rich domains and there is little to no phase where the PC₆₁BM and PIPCP are intimately mixed. We further find that on blending the scatter

SUBMITTER: Huang TY 

PROVIDER: S-EPMC9060533 | biostudies-literature | 2019 Jan

REPOSITORIES: biostudies-literature