Reduced graphene oxide decorated with octahedral NiS₂/NiS nanocrystals: facile synthesis and tunable high frequency attenuation.

ABSTRACT: Reduced graphene oxide (RGO) decorated with octahedral NiS₂/NiS nanocrystals were fabricated via a facile synthetic strategy. By appropriate adjustment of the weight ratio of GO and NiS₂/NiS nanocrystals, RGO-NiS₂/NiS nanocomposites with an excellent microwave absorption performance were achieved. As expected, RGO-NiS₂/NiS nanocomposites in a polyvinylidene fluoride (PVDF) matrix with different mass fractions (5, 10, 15, 20 wt%) possess effective absorption in the high frequency range with a thin thickness (1.5 mm) compared with those of octahedral NiS₂/NiS nanocrystals. It was revealed that RGO-NiS₂/NiS nanocomposites with a GO : NiS₂/NiS weight ratio of 1 : 4 exhibited the most prominent microwave absorption property. The optimal effective frequency bandwidth of this sample covers 4.32 GHz at a thin coating layer of 1.5 mm (15 wt%). The corresponding reflection loss value can reach -32.2 dB at 14.32 GHz. Moreover, the fundamental attenuation mechanisms are also discussed in detail.

SUBMITTER: Lu M 

PROVIDER: S-EPMC9060777 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature