A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde-alkyne-amine (A3) coupling reaction: ligand effects on the nature of the catalysis and efficiency.
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ABSTRACT:
SUBMITTER: Li YZ
PROVIDER: S-EPMC9060790 | biostudies-literature | 2019 Feb
REPOSITORIES: biostudies-literature
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A comparative study on atomically precise Au nanoclusters as catalysts for the aldehyde-alkyne-amine (A<sup>3</sup>) coupling reaction: ligand effects on the nature of the catalysis and efficiency.
Li Ying-Zhou YZ Leong Weng Kee WK
RSC advances 20190213 10
Atomically precise Au<sub>13</sub> nanoclusters stabilized by stibines catalyze the aldehyde-alkyne-amine coupling reaction more efficiently than those stabilized by thiols or phosphines. The nature of the catalytic activity is also different, and may be attributed to the weaker coordinating ability of the stibine ligands. ...[more]
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