Ultradispersed titanium dioxide nanoparticles embedded in a three-dimensional graphene aerogel for high performance sulfur cathodes.

ABSTRACT: Lithium-sulfur (Li-S) batteries are regarded as one of the most promising energy storage technologies, however, their practical application is greatly limited by a series of sulfur cathode challenges such as the notorious "shuttle effect", low conductivity and large volume change. Here, we develop a facile hydrothermal method for the large scale synthesis of sulfur hosts consisting of three-dimensional graphene aerogel with tiny TiO₂ nanoparticles (5-10 nm) uniformly dispersed on the graphene sheet (GA-TiO₂). The obtained GA-TiO₂ composites have a high surface area of ∼360 m² g^-1 and a hierarchical porous structure, which facilitates the encapsulation of sulfur in the carbon matrix. The resultant GA-TiO₂/S composites exhibit

SUBMITTER: Liu M 

PROVIDER: S-EPMC9060913 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature