Identifying the location of Cu ions in nanostructured SAPO-5 molecular sieves and its impact on the redox properties.

ABSTRACT: Combining X-ray Absorption Fine Spectroscopy (XAFS) with Anomalous Small-Angle X-ray Scattering (ASAXS) determines the location of Cu²⁺ ions in silicoaluminophosphate (SAPO-5) frameworks prepared by hydrothermal crystallization or impregnation. As expected, for the hydrothermally prepared sample, incorporation in the SAPO-5 framework was observed. For the first time preferential location of Cu²⁺ ions at the inner and outer surfaces of the framework is determined. Temperature-Programmed Reduction (TPR) and X-ray Photoelectron Spectroscopy (XPS) investigations demonstrated that such Cu²⁺ is stable in an argon (Ar) atmosphere up to 550 °C and can only be reduced under a hydrogen atmosphere. In contrast, Cu²⁺ deposited by impregnation on the pure SAP

SUBMITTER: Radnik J 

PROVIDER: S-EPMC9060918 | biostudies-literature | 2019 Feb

REPOSITORIES: biostudies-literature