A green l-cysteine modified cellulose nanocrystals biosorbent for adsorption of mercury ions from aqueous solutions.
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ABSTRACT: Using a green biosorbent to remove toxic mercury ions from aqueous solutions is a significant undertaking. In the present study, a novel biosorbent, l-cysteine modified cellulose nanocrystals (Lcys-CNCs), was prepared by functionalizing high surface area cellulose nanocrystals with l-cysteine through periodate oxidation and reductive amination reaction. Lcys-CNCs were characterized by FT-IR, 13C CP-MAS NMR, elemental analysis, XPS, zeta potential and SEM. As cellulose nanocrystals are the natural nanomaterial, and l-cysteine contains strong mercury chelating groups, Lcys-CNCs show excellent adsorption capacity for mercury ions. The experimental conditions such as pH, contact time, and initial mercury ion concentration are discussed. The pseudo-second order model can describe the
SUBMITTER: Li W
PROVIDER: S-EPMC9061121 | biostudies-literature | 2019 Feb
REPOSITORIES: biostudies-literature
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