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Highly efficient reduction of 4-nitrophenolate to 4-aminophenolate by Au/γ-Fe2O3@HAP magnetic composites.


ABSTRACT: In this article, the catalyst Au/γ-Fe2O3@hydroxyapatite (Au/γ-Fe2O3@HAP) consisting of Au nanoparticles supported on the core-shell structure γ-Fe2O3@HAP was prepared through a deposition-precipitation method. The catalyst was characterized by transmission electron microscopy, X-ray powder diffraction, X-ray photoelectron spectroscopy, Fourier transform infrared spectroscopy, N2 adsorption-desorption and atomic absorption spectrometry. The as-prepared Au/γ-Fe2O3@HAP exhibited excellent performance for the reduction of 4-nitrophenolate (4-NP) to 4-aminophenolate (4-AP) in the presence of NaBH4 at room temperature. Thermodynamic and kinetic data on the reduction of 4-NP to 4-AP catal

SUBMITTER: Xia Y 

PROVIDER: S-EPMC9062375 | biostudies-literature | 2019 Mar

REPOSITORIES: biostudies-literature