Efficient catalytic conversion of corn stalk and xylose into furfural over sulfonated graphene in γ-valerolactone.
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ABSTRACT: Sulfonated graphene (SG) was prepared and employed to convert corn stalk and xylose into furfural. Transmission electron microscopy (TEM), scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS) and Fourier transform infrared spectroscopy (FT-IR) were used to characterize SG. The effects of reaction time, temperature, substrate loading, catalyst dosage and solvents on the reaction were researched and optimized. SG exhibited high catalytic activity in the conversion of xylose and corn stalk to furfural. A fairly high furfural yield of 96% was achieved at 150 °C from xylose and a 71.9% furfural yield was obtained when using a 10.7 ratio (mass ratio: xylose to SG) at 140 °C. While a 48% furfural yield was obtained from corn stalk (based on the starting combined moles of xyl
SUBMITTER: Ma J
PROVIDER: S-EPMC9062463 | biostudies-literature | 2019 Apr
REPOSITORIES: biostudies-literature
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