Rational design of quinoxaline-based bipolar host materials for highly efficient red phosphorescent organic light-emitting diodes.

ABSTRACT: Two novel bipolar carbazole/diphenylquinoxaline-based host materials 3-(2,3-diphenylquinoxalin-6-yl)-9-phenyl-9H-carbazole (M1) and 3-(4-(2,3-diphenylquinoxalin-6-yl)phenyl)-9-phenyl-9H-carbazole (M2) have been rationally designed and synthesized. The phenyl spacer between the functionalized quinoxaline moiety and the carbazole moiety is also introduced to investigate its influence on their photophysical properties. The chemical structures, and thermal, photophysical and electrochemical properties of the two host materials were characterized and explored in detail. Red phosphorescent light-emitting diodes with M1 and M2 as hosts were prepared to explore their electroluminescent properties. Both M1 and M2 host-based red devices exhibit outstanding electroluminescent performanc

SUBMITTER: Feng Z 

PROVIDER: S-EPMC9062477 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature