Selective hydroconversion of coconut oil-derived lauric acid to alcohol and aliphatic alkane over MoO _x -modified Ru catalysts under mild conditions.

ABSTRACT: Molybdenum oxide-modified ruthenium on titanium oxide (Ru-(y)MoO _x /TiO₂; y is the loading amount of Mo) catalysts show high activity for the hydroconversion of carboxylic acids to the corresponding alcohols (fatty alcohols) and aliphatic alkanes (biofuels) in 2-propanol/water (4.0/1.0 v/v) solvent in a batch reactor under mild reaction conditions. Among the Ru-(y)MoO _x /TiO₂ catalysts tested, the Ru-(0.026)MoO _x /TiO₂ (Mo loading amount of 0.026 mmol g^-1) catalyst shows the highest yield of aliphatic n-alkanes from hydroconversion of coconut oil derived lauric acid and various aliphatic fatty acid C6-C18 precursors at 170-230 °C, 30-40 bar for 7-20 h. Over Ru-(0.02

SUBMITTER: Rodiansono 

PROVIDER: S-EPMC9062712 | biostudies-literature | 2022 Apr

REPOSITORIES: biostudies-literature