Development of moisture-proof polydimethylsiloxane/aluminum oxide film and stability improvement of perovskite solar cells using the film.

ABSTRACT: A method for enhancing the moisture barrier property of polydimethylsiloxane (PDMS) polymer films is proposed. This is achieved by filling the PDMS free volume with aluminum oxide (AlO _x ). To deposit AlO _x inside PDMS, thermal atomic layer deposition (ALD) is employed. The PDMS/AlO _x film thus produced has a 30 nm AlO _x layer on the surface. Its water vapor transmission rate (WVTR) is 5.1 × 10^-3 g m^-2 d^-1 at 45 °C and 65% relative humidity (RH). The activation energy of permeability with the PDMS/AlO _x film for moisture permeation is determined to be 35.5 kJ mol^-1. To investigate the moisture barrier capability of the PDMS/AlO _x layer, (FA

SUBMITTER: Choi EY 

PROVIDER: S-EPMC9063401 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature