Layered photochromic films stacked from spiropyran-modified montmorillonite nanosheets.

ABSTRACT: Two-dimensional (2D) nanosheets are a class of fascinating host material that demonstrates a high specific surface area for the immobilization of functional molecules. Herein, we describe a layered photochromic film using montmorillonite 2D nanosheets immobilized with spiropyran units, which demonstrates a remarkable and reversible photochromic behavior. The synthesis of the layered photochromic film includes the intercalation and exfoliation of montmorillonite powders into 2D nanosheets using a spiropyran-modified surfactant and a subsequent vacuum filtration. The photochromic units of spiropyran-modified quaternary ammonium groups are immobilized on the surface of montmorillonite 2D nanosheets through an electrostatic interaction after exchanging with the native cations in montmorillonit

SUBMITTER: Gan M 

PROVIDER: S-EPMC9063510 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature