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Identification of different carbenium ion intermediates in zeolites with identical chabazite topology via 13C-13C through-bond NMR correlations.


ABSTRACT: 13C-13C through-bond NMR correlation experiments reveal the stabilization of different carbenium ion intermediates in two zeolites possessing identical CHA topology (H-SAPO-34 and H-SSZ-13) during the methanol to olefins reaction.

SUBMITTER: Xiao D 

PROVIDER: S-EPMC9063671 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature

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Identification of different carbenium ion intermediates in zeolites with identical chabazite topology <i>via</i> <sup>13</sup>C-<sup>13</sup>C through-bond NMR correlations.

Xiao Dong D   Han Xiuwen X   Bao Xinhe X   Hou Guangjin G   Blanc Frédéric F  

RSC advances 20190423 22


<sup>13</sup>C-<sup>13</sup>C through-bond NMR correlation experiments reveal the stabilization of different carbenium ion intermediates in two zeolites possessing identical CHA topology (H-SAPO-34 and H-SSZ-13) during the methanol to olefins reaction. ...[more]

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