Three new metal coordination polymers of bifunctional imidazolate/tetrazolate bridges: the only example of a three-dimensional framework based on rare [Co4(μ3-OH)2(μ2-Cl)2]4+ mixed oxo-chloro-clusters.
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ABSTRACT: Three new metal coordination polymers [Ni(μ2-L)2(H2O)2] n (1, HL = 1-tetrazole-4-imidazole-benzene), [Co(μ2-L)2] n (2), and [Co4(μ3-OH)2(μ2-Cl)2(μ5-L)2(μ2-L)2] n ·7nH2O (3) were hydrothermally synthesized and structurally characterized. 1 displays a neutral [Ni(μ2-L)2(H2O)2] n chain built up from the Ni2+ ions bridged by deprotonated L- ligands, while 2 shows another rare neutral [Co(μ2-L)2] n chain based on Co2+ ions connec
SUBMITTER: Yang L
PROVIDER: S-EPMC9063806 | biostudies-literature | 2019 Apr
REPOSITORIES: biostudies-literature
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