What will happen when thermoresponsive poly(N-isopropylacrylamide) is tethered on poly(ionic liquid)s?

ABSTRACT: The thermoresponsive ionic liquid diblock copolymer of poly[1-(4-vinylbenzyl)-3-methylimidazolium tetrafluoroborate]-block-poly(N-isopropylacrylamide) (P[VBMI][BF₄]-b-PNIPAM) containing a hydrophilic poly(ionic liquid) block of P[VBMI][BF₄] is prepared by sequential reversible addition-fragmentation chain transfer (RAFT) polymerization. This P[VBMI][BF₄]-b-PNIPAM exhibits an abnormal thermoresponsive phase transition at a temperature above the phase transition temperature (PTT) of the PNIPAM block. For P[VBMI][BF₄]-b-PNIPAM including a short P[VBMI][BF₄] block, its aqueous solution becomes turbid at a temperature above the PTT of the thermoresponsive PNIPAM block, whereas for P[VBMI][BF₄]-<

SUBMITTER: Luo G 

PROVIDER: S-EPMC9063810 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature