A bis-benzimidazole PMO ratiometric fluorescence sensor exhibiting AIEE and ESIPT for sensitive detection of Cu².

ABSTRACT: A novel bis-benzimidazole organic siloxane precursor (BBM-Si) was prepared, and was combined with tetraethylorthosilicate (TEOS) as a mixed Si source. Then, bridged periodic mesoporous organosilica (BBM-PMO) spherical nanoparticles were synthesized by co-condensation using cetyltrimethylammonium bromide (CTAB) as structure directing agent. The optical properties showed that BBM qualifies as an "aggregation induced emission enhanced" (AIEE) molecule, exhibiting characteristics of excited-state intramolecular proton transfer (ESIPT), such as a large Stokes shift and dual fluorescence emission. For the BBM-PMO materials, the silica skeleton provides a rigid environment that limits molecular rotation, resulting in improved fluorescence emission. In particular, the BBM-PMOs exhibited dual emiss

SUBMITTER: Hao X 

PROVIDER: S-EPMC9063946 | biostudies-literature | 2019 Apr

REPOSITORIES: biostudies-literature