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Highly dispersed Ni nanoparticles on mesoporous silica nanospheres by melt infiltration for transfer hydrogenation of aryl ketones.


ABSTRACT: Nickel-based catalysts have been applied to the catalytic reactions for transfer hydrogenation of carbonyl compounds. In the present work, highly dispersed nickel particles located at the pores of mesoporous silica spheres (Ni@mSiO2) were prepared via an optimized melt infiltration route. The nickel nanoparticles of 10 wt% in the Ni@mSiO2 catalyst could be uniformly loaded with high dispersion of 36.3%, resulting excellent performance for catalytic transfer hydrogenation of aryl ketones.

SUBMITTER: Kweon H 

PROVIDER: S-EPMC9064007 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Highly dispersed Ni nanoparticles on mesoporous silica nanospheres by melt infiltration for transfer hydrogenation of aryl ketones.

Kweon Hyemin H   Jang Sanha S   Bereketova Akerke A   Chan Park Ji J   Park Kang Hyun KH   Park Kang Hyun KH  

RSC advances 20190507 25


Nickel-based catalysts have been applied to the catalytic reactions for transfer hydrogenation of carbonyl compounds. In the present work, highly dispersed nickel particles located at the pores of mesoporous silica spheres (Ni@mSiO<sub>2</sub>) were prepared <i>via</i> an optimized melt infiltration route. The nickel nanoparticles of 10 wt% in the Ni@mSiO<sub>2</sub> catalyst could be uniformly loaded with high dispersion of 36.3%, resulting excellent performance for catalytic transfer hydrogena  ...[more]

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