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Efficient one-pot green synthesis of tetrakis(acetonitrile)copper(i) complex in aqueous media.

ABSTRACT: New simple, fast, effective and environmentally friendly one-pot method for the synthesis of extensively used tetrakis(acetonitrile)copper(i) complexes with BF4 -, PF6 - and ClO4 - counterions is invented and optimized. The approach suggested allows using water as solvent and minimizes amounts of toxic organic reagents in the synthetic protocol.

SUBMITTER: Kritchenkov IS 

PROVIDER: S-EPMC9064342 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Efficient one-pot green synthesis of tetrakis(acetonitrile)copper(i) complex in aqueous media.

Kritchenkov Ilya S IS   Shakirova Julia R JR   Tunik Sergey P SP  

RSC advances 20190517 27

New simple, fast, effective and environmentally friendly one-pot method for the synthesis of extensively used tetrakis(acetonitrile)copper(i) complexes with BF<sub>4</sub> <sup>-</sup>, PF<sub>6</sub> <sup>-</sup> and ClO<sub>4</sub> <sup>-</sup> counterions is invented and optimized. The approach suggested allows using water as solvent and minimizes amounts of toxic organic reagents in the synthetic protocol. ...[more]

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