Enhanced luminescence and tunable magnetic properties of lanthanide coordination polymers based on fluorine substitution and phenanthroline ligand.
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ABSTRACT: A family of highly stable lanthanide coordination polymers incorporating fluorine-substituted carboxylate tectonics and the rigid ligand phenanthroline, namely, {[Ln m (Tfbda) n (Phen)2·2H2O]·2H2O} z , (Ln = Pr (1), Ho (4) and Gd (7), m = 2, n = 3); {[Ln3 (Tfbda) m 1 (Tfba) m 2 (Phen) n ·2H2O]·H2O} z (z > 1, Ln = Dy (3), Er (5) and Yb (6), m 1 = 4, m 2 = 1, n = 3); [Ln2(H2Tfbda)4(Phen)2·(H2O)2]·Phen (Ln = Nd (2)), Tfbda = 3,4,5,6-tetrafluoro-benzene-1,
SUBMITTER: Feng X
PROVIDER: S-EPMC9064376 | biostudies-literature | 2019 May
REPOSITORIES: biostudies-literature
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