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Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates.


ABSTRACT: A facile and efficient approach to phosphoramidates was developed via amination of phosphoryl azides. A variety of phosphoramidates were obtained in one step with good to excellent yields under a mild reaction system. The process uses easily available amines as a N source and offers a new opportunity for P-N bond formation.

SUBMITTER: Li Q 

PROVIDER: S-EPMC9064390 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Transition-metal-free amination phosphoryl azide for the synthesis of phosphoramidates.

Li Qing Q   Sun Xiaohua X   Yang Xiaoqin X   Wu Minghu M   Sun Shaofa S   Chen Xiuling X  

RSC advances 20190522 28


A facile and efficient approach to phosphoramidates was developed <i>via</i> amination of phosphoryl azides. A variety of phosphoramidates were obtained in one step with good to excellent yields under a mild reaction system. The process uses easily available amines as a N source and offers a new opportunity for P-N bond formation. ...[more]

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