A nonlinear optical switch induced by an external electric field: inorganic alkaline-earth alkalide.

ABSTRACT: Exploring a new type of nonlinear optical switch molecule with excess electron character is extremely important for promoting the application of excess electron compounds in the nonlinear optical (NLO) field. Here, we report external electric field (EEF) induced second-order NLO switch molecules of inorganic alkaline-earth alkalides, M(NH₃)₆Na₂ (M = Mg or Ca). The centrosymmetric structure of M(NH₃)₆Na₂ is destroyed in the presence of an EEF, and then a long-range charge transfer process occurs. It has been found that excess electrons are gradually transferred from one Na atom to the other Na atom through the inorganic metal cluster M(NH₃)₆. Finally, the excess electrons are completely located on one of

SUBMITTER: Li B 

PROVIDER: S-EPMC9064415 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature