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Plasma surface-modification of cellulose nanocrystals: a green alternative towards mechanical reinforcement of ABS.


ABSTRACT: This article proposes a strategy to functionalize cellulose nanocrystals by means of plasma-surface modification utilizing monomers of different nature: caprolactone, styrene and farnesene. The surface characteristics of the nanocrystals were studied by different techniques including XPS, FTIR and STEM, demonstrating that this technique allows a successful functionalization, yielding homogenous functionalization which does not alter the rod-like shape of the nanocrystals, and therefore their anisotropic behavior. We have furthermore studied the employment of the modified nanocrystals as reinforcement additive of ABS, which significantly enhanced the impact resistance of the thermoplastic, which could have great implications for industrial applications.

SUBMITTER: Alanis A 

PROVIDER: S-EPMC9064589 | biostudies-literature | 2019 May

REPOSITORIES: biostudies-literature

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Plasma surface-modification of cellulose nanocrystals: a green alternative towards mechanical reinforcement of ABS.

Alanis Andrés A   Valdés Josué Hernández JH   María Guadalupe Neira-Velázquez NV   Lopez Ricardo R   Mendoza Ricardo R   Mathew Aji P AP   Díaz de León Ramón R   Valencia Luis L  

RSC advances 20190501 30


This article proposes a strategy to functionalize cellulose nanocrystals by means of plasma-surface modification utilizing monomers of different nature: caprolactone, styrene and farnesene. The surface characteristics of the nanocrystals were studied by different techniques including XPS, FTIR and STEM, demonstrating that this technique allows a successful functionalization, yielding homogenous functionalization which does not alter the rod-like shape of the nanocrystals, and therefore their ani  ...[more]

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