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One-step electrodeposition of cerium-doped nickel hydroxide nanosheets for effective oxygen generation.


ABSTRACT: Efficient electrocatalysts catalyzing oxygen evolution reaction (OER) in alkaline media is highly desirable for large-scale hydrogen production from water splitting. Here we report the direct electrodeposition of cerium-doped nickel hydroxide nanosheets on carbon fiber paper and its prominent performance in catalyzing the OER. The composite generates a current density of 100 mA cm-2 at an overpotential of 320 mV, rivaling the performance of most reported OER catalysts and commercially available RuO2. X-ray photoelectron spectroscopy analysis shows strong electronic interaction between Ni(OH)2 and CeO2, making a great contribution to the OER enhancement.

SUBMITTER: Fang G 

PROVIDER: S-EPMC9064652 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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One-step electrodeposition of cerium-doped nickel hydroxide nanosheets for effective oxygen generation.

Fang Gang G   Cai Jinhua J   Huang Zhipeng Z   Zhang Chi C  

RSC advances 20190606 31


Efficient electrocatalysts catalyzing oxygen evolution reaction (OER) in alkaline media is highly desirable for large-scale hydrogen production from water splitting. Here we report the direct electrodeposition of cerium-doped nickel hydroxide nanosheets on carbon fiber paper and its prominent performance in catalyzing the OER. The composite generates a current density of 100 mA cm<sup>-2</sup> at an overpotential of 320 mV, rivaling the performance of most reported OER catalysts and commercially  ...[more]

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