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Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C-H activation.

ABSTRACT: Site-selective synthesis of C-7 arylated indolines has been achieved via oxidative arylation of indolines with arylsilanes under Rh(iii)-catalyzed C-H activation of indolines by using CuSO₄ as a co-oxidant. This transformation has been explored for a wide range of substrates under mild conditions.

SUBMITTER: Luo H

PROVIDER: S-EPMC9064675 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Rh(iii)-catalyzed C-7 arylation of indolines with arylsilanes via C-H activation.

Luo Haiqing H Xie Qi Q Sun Kai K Deng Jianbo J Xu Lin L Wang Kejun K Luo Xuzhong X

RSC advances 20190610 32

Site-selective synthesis of C-7 arylated indolines has been achieved via oxidative arylation of indolines with arylsilanes under Rh(iii)-catalyzed C-H activation of indolines by using CuSO4 as a co-oxidant. This transformation has been explored for a wide range of substrates under mild conditions. ...[more]

PMID: 35515217

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