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Tailor-made high-performance reverse osmosis membranes by surface fixation of hydrophilic macromolecules for wastewater treatment.

ABSTRACT: Polyamide aromatic (PA) reverse osmosis (RO) membranes are currently the most important materials in the seawater desalination and wastewater treatment industry. This study used hydrophilic macromolecular polyvinylpyrrolidone (PVP) in a PA selective layer to develop a new polyamide thin-film composite (TFC), namely PA-g-PVP RO, which will be used for water treatment. The TFC is prepared via an interfacial polymerisation process, and TFC-based PVP can be transplanted on a PA surface by radiation. PA-g-PVP RO was characterised by ATR-FTIR, SEM, XPS, AFM and contact angle test and then evaluated by determining its permeability, salt retention and antifouling performance, among other properties. Results show that the chemical composition and surface morphology of the polyamide film significantly changed. A PVP brush grafted on an RO membrane surface significantly enhanced the hydrophilicity and antifouling performance of the membrane. When the PVP concentration was increased in an aqueous solution to 2%, the water contact angle of the sacrificial layer of the modified membrane decreased to 24.3°, the fouling recovery ratio to 93.4% and the salt retention increased to 99.5% at a small flux change. This combined technology can also be used for other macromolecules to modify the membrane and study the preparation and modification of ultra-filtration and nano-filtration membranes.

SUBMITTER: Liu C

PROVIDER: S-EPMC9064689 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Tailor-made high-performance reverse osmosis membranes by surface fixation of hydrophilic macromolecules for wastewater treatment.

Liu Chao C Guo Yongqiang Y Zhang Jiaming J Tian Bo B Lin Oukai O Liu Yawei Y Zhang Chunhua C

RSC advances 20190606 31

Polyamide aromatic (PA) reverse osmosis (RO) membranes are currently the most important materials in the seawater desalination and wastewater treatment industry. This study used hydrophilic macromolecular polyvinylpyrrolidone (PVP) in a PA selective layer to develop a new polyamide thin-film composite (TFC), namely PA-<i>g</i>-PVP RO, which will be used for water treatment. The TFC is prepared <i>via</i> an interfacial polymerisation process, and TFC-based PVP can be transplanted on a PA surface ...[more]

PMID: 35520574

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Project description:Many companies in the food industry apply reverse osmosis (RO) membranes to ensure high-quality reuse of water. Biofouling is however, a common, recalcitrant and recurring problem that blocks transport over membranes and decreases the water recovery. Microorganisms adhering to membranes may form biofilm and produce an extracellular matrix, which protects against external stress and ensures continuous attachment. Thus, various agents are tested for their ability to degrade and disperse biofilms. Here, we identified industrially relevant bacterial model communities that form biofilms on RO membranes used for treating process water before reuse. There was a marked difference in the biofilm forming capabilities of bacteria isolated from contaminated RO membranes. One species, Raoultella ornithinolytica, was particularly capable of forming biofilm and was included in most communities. The potential of different enzymes (Trypsin-EDTA, Proteinase K, α-Amylase, β-Mannosidase and Alginate lyase) as biofouling dispersing agents was evaluated at different concentrations (0.05 U/ml and 1.28 U/ml). Among the tested enzymes, β-Mannosidase was the only enzyme able to reduce biofilm formation significantly within 4 h of exposure at 25 °C (0.284 log reduction), and only at the high concentration. Longer exposure duration, however, resulted in significant biofilm reduction by all enzymes tested (0.459-0.717 log reduction) at both low and high concentrations. Using confocal laser scanning microscopy, we quantified the biovolume on RO membranes after treatment with two different enzyme mixtures. The application of proteinase K and β-Mannosidase significantly reduced the amount of attached biomass (43% reduction), and the combination of all five enzymes showed even stronger reducing effect (71% reduction). Overall, this study demonstrates a potential treatment strategy, using matrix-degrading enzymes for biofouled RO membranes in food processing water treatment streams. Future studies on optimization of buffer systems, temperature and other factors could facilitate cleaning operations based on enzymatic treatment extending the lifespan of membranes with a continuous flux.

Dataset Information

Tailor-made high-performance reverse osmosis membranes by surface fixation of hydrophilic macromolecules for wastewater treatment.

Publications

Tailor-made high-performance reverse osmosis membranes by surface fixation of hydrophilic macromolecules for wastewater treatment.

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