Tetrathiafulvalene: effective organic anodic materials for WO₃-based electrochromic devices.

ABSTRACT: Finding a new, effective anodic species is a challenge for achieving simpler low-voltage tungsten trioxide (WO₃)-based electrochromic devices (ECDs). In this work, we utilize tetrathiafulvalene (TTF) and demonstrate its reversible redox behaviors as an electrolyte-soluble anodic species. The concentration of TTF in the electrolyte is varied to optimize device performance. When the TTF concentration is low (0.01 M), a smaller maximum transmittance difference (ΔT _max ∼ 34.2%) and coloration efficiency (η ∼ 59.6 cm² C^-1) are measured. Although a better performance of ΔT _max ∼ 93.7% and η ∼ 74.5 cm² C^-1 is achieved at 0.05 M TTF, the colored state could no longer return to its original form. We conclude that 0.03 M of TTF is the appropriate concentration for high-performance WO₃ ECDs with high optical contrast and reversible EC behaviors. The irreversible EC transition at high concentrations of TTF is attributed to the agglomeration of TTF molecules.

SUBMITTER: Kim YM 

PROVIDER: S-EPMC9065372 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature