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Self-assembly of chemically modified graphene sheets in an external magnetic field.

ABSTRACT: The rapid developments of effective self-assembly technologies indicated that ordered structures could be produced using external field inducement. We designed the alignment of graphene oxide nanosheets grafted with the modified ferroferric oxide by the application of a magnetic field. The results indicated that the morphologies of graphene oxide went through some changes from disordered to semi-ordered in the final and, highly oriented wrinkled structures. The orientation mechanism of graphene oxide demonstrated that the geometric features of the wrinkles were related to the edge stresses and the elastic stiffness of the sheets, magnetic force of magnetic field to magnetic-particles. The prepared reduced graphene oxide fibers indicated that the sheets with magnetic precipitates underwent shrinkage in the radial direction when an external magnetic field was exerted and the interior sheets aligned along the direction of the magnetic field, which was supported by the proposed theories. It is expected that the research could contribute to the applications of flexible graphene-based materials in preparation and controlling the formation of wrinkles in single layer graphene.

SUBMITTER: Tong M

PROVIDER: S-EPMC9065386 | biostudies-literature | 2019 Jun

REPOSITORIES: biostudies-literature

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Self-assembly of chemically modified graphene sheets in an external magnetic field.

Tong Mingqiong M Cao Jianda J Chen Xiaoping X Zhang Huanxia H Wu Wen W Ma Hui H

RSC advances 20190621 34

The rapid developments of effective self-assembly technologies indicated that ordered structures could be produced using external field inducement. We designed the alignment of graphene oxide nanosheets grafted with the modified ferroferric oxide by the application of a magnetic field. The results indicated that the morphologies of graphene oxide went through some changes from disordered to semi-ordered in the final and, highly oriented wrinkled structures. The orientation mechanism of graphene ...[more]

PMID: 35519407

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Project description:While the green production and application of 2D functional nanomaterials, such as graphene flakes, in films for stretchable and wearable technologies is a promising platform for advanced technologies, there are still challenges involved in the processing of the deposited material to improve properties such as electrical conductivity. In applications such as wearable biomedical and flexible energy devices, the widely used flexible and stretchable substrate materials are incompatible with high-temperature processing traditionally employed to improve the electrical properties, which necessitates alternative manufacturing approaches and new steps for enhancing the film functionality. We hypothesize that a mechanical stimulus, in the form of substrate straining, may provide such a low-energy approach for modifying deposited film properties through increased flake packing and reorientation. To this end, graphene flakes were exfoliated using an unexplored combination of ethanol and cellulose acetate butyrate for morphological and percolative electrical characterization prior to application on polydimethylsiloxane (PDMS) substrates as a flexible and stretchable electrically conductive platform. The deposited percolative free-standing films on PDMS were characterized via in situ resistance strain monitoring and surface morphology measurements over numerous strain cycles, with parameters extracted describing the dynamic modulation of the film's electrical properties. A reduction in the film resistance and strain gauge factor was found to correlate with the surface roughness and densification of a sample's (sub)surface and the applied strain. High surface roughness samples exhibited enhanced reduction in resistance as well as increased sensitivity to strain compared to samples with low surface roughness, corresponding to surface smoothing, which is related to the dynamic settling of graphene flakes on the substrate surface. This procedure of incorporating strain as a mechanical stimulus may find application as a manufacturing tool/step for the routine fabrication of stretchable and wearable devices, as a low energy and compatible approach, for enhancing the properties of such devices for either high sensitivity or low sensitivity of electrical resistance to substrate strain.

Dataset Information

Self-assembly of chemically modified graphene sheets in an external magnetic field.

Publications

Self-assembly of chemically modified graphene sheets in an external magnetic field.

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