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Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)₂ followed by the formation of molecular poly-oxo cluster {U₁₄} containing hemimellitate uranium(iv).

ABSTRACT: Two coordination compounds bearing tetravalent uranium were synthesized in the presence of tritopic hemimellitic acid in acetonitrile with a controlled amount of water (H₂O/U ≈ 8) and structurally characterized. Compound 1, [U(1,2,3-Hbtc)₂]·0.5CH₃CN is constructed around an eight-fold coordinated uranium cationic unit [UO₈] linked by the poly-carboxylate ligands to form dimeric subunits, which are further connected to form infinite corrugated ribbons and a three-dimensional framework. Compound 2, [U₁₄O₈(OH)₄Cl₈(H₂O)₁₆(1,2,3-Hbtc)₈(ox)₄(ac)₄] ({U₁₄}) exhibits an unprecedented polynuclear {U₁₄} poly-oxo uranium cluster surrounded

SUBMITTER: Dufaye M

PROVIDER: S-EPMC9067251 | biostudies-literature | 2019 Jul

REPOSITORIES: biostudies-literature

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Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)₂ followed by the formation of molecular poly-oxo cluster {U₁₄} containing hemimellitate uranium(iv).

OmicsDI is part of the ELIXIR infrastructure

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Dataset Information

Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)2 followed by the formation of molecular poly-oxo cluster {U14} containing hemimellitate uranium(iv).

OmicsDI is part of the ELIXIR infrastructure

Tweets

Time-controlled synthesis of the 3D coordination polymer U(1,2,3-Hbtc)₂ followed by the formation of molecular poly-oxo cluster {U₁₄} containing hemimellitate uranium(iv).