Crystal structure of di-μ-chlorido-bis-{chlorido-[(-)-5,6-pinenebi-pyridine]-cobalt(II)} aqua-dichlorido[(-)-5,6-pinenebi-pyridine]cobalt(II).

ABSTRACT: The crystal structure of [Co₂Cl₄(C₁₇H₁₈N₂)₂][CoCl₂(C₁₇H₁₈N₂)(H₂O)] or [Co(L)Cl(μ-Cl)]₂[Co(L)(Cl)₂(OH₂)], where L is the enanti-opure bidentate ligand (-)-5,6-pinenebi-pyridine (C₁₇H₁₈N₂), has been determined. Crystals suitable for X-ray structure analysis were obtained by slow evaporation of an ethano-lic solution containing equimolar amounts of L and CoCl₂·6H₂O. The Co^II cations all have a coordination number of five, and in each case the coordination polyhedron is a trigonal bipyramid. The Co-N bonds lengths range from 2.037 (7) to 2.195 (7) Å,

SUBMITTER: Varisco M 

PROVIDER: S-EPMC9069521 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature