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ABSTRACT:
SUBMITTER: Ilichev VA
PROVIDER: S-EPMC9069573 | biostudies-literature | 2019 Aug
REPOSITORIES: biostudies-literature
Ilichev Vasily A VA Silantyeva Liubov I LI Grishin Ivan D ID Rozhkov Anton V AV Rumyantcev Roman V RV Fukin Georgy K GK Bochkarev Mikhail N MN
RSC advances 20190805 42
In order to obtain molecular Ce(iii) complexes which emit red light by f-d transitions the azolyl-substituted thiophenolates were used as the ligands. The thiophenolate Ce(iii) complexes were synthesized by the reaction of Ce[N(SiMe<sub>3</sub>)<sub>2</sub>]<sub>3</sub> with respective thiophenols 2-(2'-mercaptophenyl)benzimidazole (H(NSN)), 2-(2'-mercaptophenyl)benzoxazole (H(OSN)) and 2-(2'-mercaptophenyl)benzothiazole (H(SSN)) in DME media. The structures of the benzimidazolate (Ce(NSN)<sub>3 ...[more]