CO₂ Capture and Low-Temperature Release by Poly(aminoethyl methacrylate) and Derivatives.

ABSTRACT: Poly(aminoethyl methacrylate) (PAEMA), poly(ethylene oxide)-block-(aminoethyl methacrylate) (PEO-PAEMA), and their guanidinylated derivates, poly(guanidine ethyl methacrylate) (PGEMA) and poly(ethylene oxide)-block-(guanidine ethyl methacrylate) (PEO-PGEMA), were prepared to study their capabilities for CO₂ adsorption and release. The polymers of different forms or degree of guanidinylation were thoroughly characterized, and their interaction with CO₂ was studied by NMR and calorimetry. The extent and kinetics of adsorption and desorption of N₂ and CO₂ were investigated by thermogravimetry under controlled gas atmospheres. The materials did not adsorb N₂, whereas CO₂ could be reversibly adsorbed at room tempera

SUBMITTER: Tiainen T 

PROVIDER: S-EPMC9069862 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature