Dataset Information

CO₂ Capture and Low-Temperature Release by Poly(aminoethyl methacrylate) and Derivatives.

ABSTRACT: Poly(aminoethyl methacrylate) (PAEMA), poly(ethylene oxide)-block-(aminoethyl methacrylate) (PEO-PAEMA), and their guanidinylated derivates, poly(guanidine ethyl methacrylate) (PGEMA) and poly(ethylene oxide)-block-(guanidine ethyl methacrylate) (PEO-PGEMA), were prepared to study their capabilities for CO₂ adsorption and release. The polymers of different forms or degree of guanidinylation were thoroughly characterized, and their interaction with CO₂ was studied by NMR and calorimetry. The extent and kinetics of adsorption and desorption of N₂ and CO₂ were investigated by thermogravimetry under controlled gas atmospheres. The materials did not adsorb N₂, whereas CO₂ could be reversibly adsorbed at room temperature and released by an elevated temperature. The most promising polymer was PGEMA with a guanidinylation degree of 7% showing a CO₂ adsorption capacity of 2.4 mmol/g at room temperature and a desorption temperature of 72 °C. The study also revealed relations between the polymer chemical composition and CO₂ adsorption and release characteristics that are useful in future formulations for CO₂ adsorbent polymer materials.

SUBMITTER: Tiainen T

PROVIDER: S-EPMC9069862 | biostudies-literature | 2022 May

REPOSITORIES: biostudies-literature

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CO2 Capture and Low-Temperature Release by Poly(aminoethyl methacrylate) and Derivatives.

Tiainen Tony T Mannisto Jere K JK Tenhu Heikki H Hietala Sami S

Langmuir : the ACS journal of surfaces and colloids 20211208 17

Poly(aminoethyl methacrylate) (PAEMA), poly(ethylene oxide)-block-(aminoethyl methacrylate) (PEO-PAEMA), and their guanidinylated derivates, poly(guanidine ethyl methacrylate) (PGEMA) and poly(ethylene oxide)-block-(guanidine ethyl methacrylate) (PEO-PGEMA), were prepared to study their capabilities for CO2 adsorption and release. The polymers of different forms or degree of guanidinylation were thoroughly characterized, and their interaction with CO2 was stud ...[more]

PMID: 34879650

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Project description:Due to the dramatically increased atmospheric CO2 concentration and consequential climate change, significant effort has been made to develop sorbents to directly capture CO2 from ambient air (direct air capture, DAC) to achieve negative CO2 emissions in the immediate future. However, most developed sorbents have been studied under a limited array of temperature (>20 °C) and humidity conditions. In particular, the dearth of experimental data on DAC at sub-ambient conditions (e.g., -30 to 20 °C) and under humid conditions will severely hinder the large-scale implementation of DAC because the world has annual average temperatures ranging from -30 to 30 °C depending on the location and essentially no place has a zero absolute humidity. To this end, we suggest that understanding CO2 adsorption from ambient air at sub-ambient temperatures, below 20 °C, is crucial because colder temperatures represent important practical operating conditions and because such temperatures may provide conditions where new sorbent materials or enhanced process performance might be achieved. Here we demonstrate that MIL-101(Cr) materials impregnated with amines (TEPA, tetraethylenepentamine, or PEI, poly(ethylenimine)) offer promising adsorption and desorption behavior under DAC conditions in both the presence and absence of humidity under a wide range of temperatures (-20 to 25 °C). Depending on the amine loading and adsorption temperature, the sorbents show different CO2 capture behavior. With 30 and 50 wt % amine loadings, the sorbents show weak and strong chemisorption-dominant CO2 capture behavior, respectively. Interestingly, at -20 °C, the CO2 adsorption capacity of 30 wt % TEPA-impregnated MIL-101(Cr) significantly increased up to 1.12 mmol/g from 0.39 mmol/g at ambient conditions (25 °C) due to the enhanced weak chemisorption. More importantly, the sorbents also show promising working capacities (0.72 mmol/g) over 15 small temperature swing cycles with an ultralow regeneration temperature (-20 °C sorption to 25 °C desorption). The sub-ambient DAC performance of the sorbents is further enhanced under humid conditions, showing promising and stable CO2 working capacities over multiple humid small temperature swing cycles. These results demonstrate that appropriately designed DAC sorbents can operate in a weak chemisorption modality at low temperatures even in the presence of humidity. Significant energy savings may be realized via the utilization of small temperature swings enabled by this weak chemisorption behavior. This work suggests that significant work on DAC materials that operate at low, sub-ambient temperatures is warranted for possible deployment in temperate and polar climates.

Project description:Rising CO2 emissions are responsible for increasing global temperatures causing climate change. Significant efforts are underway to develop amine-based sorbents to directly capture CO2 from air (called direct air capture (DAC)) to combat the effects of climate change. However, the sorbents' performances have usually been evaluated at ambient temperatures (25 °C) or higher, most often under dry conditions. A significant portion of the natural environment where DAC plants can be deployed experiences temperatures below 25 °C, and ambient air always contains some humidity. In this study, we assess the CO2 adsorption behavior of amine (poly(ethyleneimine) (PEI) and tetraethylenepentamine (TEPA)) impregnated into porous alumina at ambient (25 °C) and cold temperatures (-20 °C) under dry and humid conditions. CO2 adsorption capacities at 25 °C and 400 ppm CO2 are highest for 40 wt% TEPA-incorporated γ-Al2O3 samples (1.8 mmol CO2/g sorbent), while 40 wt % PEI-impregnated γ-Al2O3 samples exhibit moderate uptakes (0.9 mmol g-1). CO2 capacities for both PEI- and TEPA-incorporated γ-Al2O3 samples decrease with decreasing amine content and temperatures. The 40 and 20 wt % TEPA sorbents show the best performance at -20 °C under dry conditions (1.6 and 1.1 mmol g-1, respectively). Both the TEPA samples also exhibit stable and high working capacities (0.9 and 1.2 mmol g-1) across 10 cycles of adsorption-desorption (adsorption at -20 °C and desorption conducted at 60 °C). Introducing moisture (70% RH at -20 and 25 °C) improves the CO2 capacity of the amine-impregnated sorbents at both temperatures. The 40 wt% PEI, 40 wt % TEPA, and 20 wt% TEPA samples show good CO2 uptakes at both temperatures. The results presented here indicate that γ-Al2O3 impregnated with PEI and TEPA are potential materials for DAC at ambient and cold conditions, with further opportunities to optimize these materials for the scalable deployment of DAC plants at different environmental conditions.

Dataset Information

CO₂ Capture and Low-Temperature Release by Poly(aminoethyl methacrylate) and Derivatives.

Publications

CO<sub>2</sub> Capture and Low-Temperature Release by Poly(aminoethyl methacrylate) and Derivatives.

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