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Triazole-based novel bis Schiff base colorimetric and fluorescent turn-on dual chemosensor for Cu2+ and Pb2+: application to living cell imaging and molecular logic gates.


ABSTRACT: A triazole-based novel bis Schiff base colorimetric and fluorescent chemosensor (L) has been designed, synthesized and characterized by elemental analysis, 1H-NMR, ESI-MS, FTIR spectra and DFT studies. The receptor L showed selective and sensitive colorimetric sensing ability for Cu2+ and Pb2+ ions by changing color from colorless to yellow and light yellow respectively in CH3OH-tris-buffer (1 : 1, v/v). However, it displayed strong fluorescence enhancement upon the addition of both Cu2+ and Pb2+ ions, attributed to the blocking of PET. The fluorometric detection limits for Cu2+ and Pb2+ were found to be 12 × 10-7 M and 9 × 10-7 M and the colorimetric detection limits were 3.7 × 10

SUBMITTER: Rout K 

PROVIDER: S-EPMC9070313 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature