Design and synthesis of stable indigo polymer semiconductors for organic field-effect transistors with high fluoride sensitivity and selectivity.

ABSTRACT: We report the design and synthesis of two novel indigo donor-acceptor (D-A) polymers, PIDG-T-C20 and PIDG-BT-C20, comprising an indigo moiety that has intramolecular hydrogen-bonds as the acceptor building block and thiophene (T) and bithiophene (BT) as the donor building block, respectively. PIDG-T-C20 and PIDG-BT-C20 exhibited characteristic p-type semiconductor performance, achieving hole mobilities of up to 0.016 and 0.028 cm² V^-1 s^-1, respectively, which are highest values reported for indigo-based polymers. The better performing PIDG-BT-C20 was used for the fabrication of water-gated organic field-effect transistors (WGOFETs), which showed excellent stability at ambient conditions. The PIDG-BT-C20-based WGOFETs exhibited rapid response when fluoride i

SUBMITTER: Ngai JHL 

PROVIDER: S-EPMC9070390 | biostudies-literature | 2019 Aug

REPOSITORIES: biostudies-literature