Kinetics of fluoride-catalysed synthesis of organosilica colloids in aqueous solutions of amphiphiles.

ABSTRACT: Reactions involving hydrophobic reactants in water can be much accelerated in organic solvent-free solutions containing amphiphiles at neutral pH and room temperature. Previously, we demonstrated that organosilica colloidal particles could be conveniently synthesized by a versatile salt-catalysis method in solutions modified with various amphiphilic molecules. The method precludes the use of any solvent, any added form of energy (thermal or mechanical), and any strong (or hazardous) acids/bases. Herein, the kinetic properties of the reaction were systematically investigated for fluoride-catalysed synthesis of colloidal organosilica from a thiol-functionalized organosilane precursor, (3-mercaptopropyl)trimethoxysilane. Continuous, real-time ATR-FTIR measurements allowed probing the time evo

SUBMITTER: Hu TM 

PROVIDER: S-EPMC9070784 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature