Hexanuclear Cu₃O-3Cu triazole-based units as novel core motifs for high nuclearity copper(ii) frameworks.

ABSTRACT: The asymmetric 3,5-disubstituted 1,2,4-triazole ligand H₂V (5-amino-3-picolinamido-1,2,4-triazole) by reaction with an excess of Cu(ii) perchlorate (Cu : H₂V being 12 : 1) has produced a novel hexanuclear {Cu₆(μ₃-O/H)(HV/V)₃} fragment, with one triangular Cu₃(μ₃-O/H) group connected to three peripheral single Cu(ii) ions through a cis-cis-trans bridging mode of the ligand, which is the building block of the three structures described here: one hexanuclear, [Cu₆(μ₃-O)(HV)₃(ClO₄)₇(H₂O)₉]·8H₂O (1), one dodecanuclear, [Cu₁₂(μ₃-O)₂(V)₆(ClO₄)₅(H

SUBMITTER: Ferrer S 

PROVIDER: S-EPMC9071962 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature