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KO ^t Bu-promoted oxidative dimerizations of 2-methylquinolines to 2-alkenyl bisquinolines with molecular oxygen.

ABSTRACT: KO ^t Bu-promoted oxidative dimerizations of 2-methylquinolines with molecular oxygen as the oxidant have been developed for the first time. The mild reaction conditions allow the homo- and cross-dimerizations of 2-methylquinolines to give functionalized 2-alkenyl bisquinolines in highly trans-selective manners.

SUBMITTER: Wang Z

PROVIDER: S-EPMC9072141 | biostudies-literature | 2019 Sep

REPOSITORIES: biostudies-literature

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KO t Bu-promoted oxidative dimerizations of 2-methylquinolines to 2-alkenyl bisquinolines with molecular oxygen.

Wang Zhen Z Zhang Jinjin J Shi Jianxue J Wang Huiqiao H

RSC advances 20190923 52

KO t Bu-promoted oxidative dimerizations of 2-methylquinolines with molecular oxygen as the oxidant have been developed for the first time. The mild reaction conditions allow the homo- and cross-dimerizations of 2-methylquinolines to give functionalized 2-alkenyl bisquinolines in highly trans-selective manners. ...[more]

PMID: 35530195

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